多壁碳管/ 二氧化钛改性棉织物及其自清洁和抗紫外性能
Multi-wall carbon nanotubes and nano titanium dioxide coated on cotton fabric for superior self-cleaning and UV blocking
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摘要: 以丁二酸为交联剂,采用纳米TiO2 和多壁碳管对棉织物进行改性。通过暴露于紫外和阳光照射,分析Direct Green 6 浓度的减少来评价改性织物的光催化自洁性能。探讨样品的紫外吸收、耐磨性与扩张强度。结果表明,在紫外和阳光照射下,经纳米TiO2 和多壁碳管处理后的棉织物能有效提高Direct Green 6 的光降解效率。改性织物的耐麿性和抗紫外性能提高,抗张强度略降低。Direct Green 6 光降解效率的提高归因于电子空穴对重组的减少及由TiO2 和多壁碳管产生协同作用而使吸收光的增加。Abstract: Cotton fabrics were treated with nano titanium dioxide and multi-wall carbon nanotubes (MWCNTs) using succinic acid as a crosslinking agent. The photocatalytic self-cleaning properties of the samples were assessed by analyzing the degradation of Direct Green 6 under UV and sunlight. The UV absorption, abrasion resistance and tensile strength of the treated fabric were measured. It was found that coating the cotton fabrics with both MWCNTs and nano titanium dioxide effectively improves the photodeg radation efficiency of Direct Green 6 under both UV and sunlight. The abrasion resistance and UV blocking capability are improved, and tensile strength decreases a little after the coating. The increased photodegradation of Direct Green 6 can be ascribed to enhanced adsorption, a reduced electronhole pair recombination rate and an extended light absorption wavelength as a result of the joint action of nano titanium dioxide and MWCNTs.